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Pungent vanilloids such as capsaicin (trans-8-methyl-N-vanillyl-6-nonenamide), a major pungent of hot chili pepper ( Capsicum annuum ) [206, 223], and (10)-shogaol from ginger ( Zingiber officinale ) also activate phase II detoxification enzyme expression in a Nrf2-dependent manner [207]

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Its uniqueness lies in the direct triggering by excessive accumulation of Cu + within mitochondria and the specific targeting of lipoylated metabolic enzymes in the tricarboxylic acid cycle, leading to the loss of enzyme function, protein aggregation, and mitochondrial metabolic collapse

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