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The fourth step of the mechanism consists of a second Tyr9 rearrangement that allows direct interaction of the Tyr9 phenolate with the glutathione thiol

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2.2 Terpenoids and saponins: lipophilicity advantages and precise modulation of intracellular targets In contrast to polyphenols, terpenoids are synthesized via the polymerization of isoprene units and typically exhibit strong lipophilicity